This guide will help you though the process of converting a System Center 2012 Configuration Manager (SCCM) Evaluation, to a Full Product Version.
From the start menu navigate to All Programs -> Microsoft System Center 2012 -> Configuration Manager, and select Configuration Manager Setup.
Select Perform site maintenance or reset this Site, and click Next.
Select Convert from Evaluation to Full Product Version, and enter your 25-character product key, and click Next.
Volume License Customers can find the product key here: https://www.microsoft.com/licensing/servicecenter/default.aspx
(AFAIK all volume license customers has the same key for all System Center 2012 products).
Accept the license terms, and you’re done…